TY - JOUR
T1 - Conformational studies on aldonolactones by n.m.r. spectroscopy. Conformations of d-glucono-1,5-lactone and d-mannono-1,5-lactone in solution
AU - Wałaszek, Zbigniew
AU - Horton, Derek
AU - Ekiel, Irena
N1 - Funding Information:
*This work was supported, in part, by NSF Grant MPS-72-04609-A01 tFor a preliminary report, see ref. 1. tPresent address: Department of Tumor Biology, Institute of Oncology, Gliwice, 44-100 Poland. **To whom inquiries shouId be addressed. tiPresent address: Department of Biophysics, institute of Experimental Physics, University of Warsaw, Warsaw, 02-089 Poland.
PY - 1982/8/16
Y1 - 1982/8/16
N2 - The conformations of d-glucono-1,5-lactone (1) and d-mannono-1,5-lactone (2) in solution were investigated by 1H- and 13C-n.m.r. spectroscopy. Conformational equilibria for 1 and 2 were found to lie strongly in favor of the 4H3(d),gg and B2,5(d),gg conformations, respectively.
AB - The conformations of d-glucono-1,5-lactone (1) and d-mannono-1,5-lactone (2) in solution were investigated by 1H- and 13C-n.m.r. spectroscopy. Conformational equilibria for 1 and 2 were found to lie strongly in favor of the 4H3(d),gg and B2,5(d),gg conformations, respectively.
UR - http://www.scopus.com/inward/record.url?scp=0001226736&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0001226736&partnerID=8YFLogxK
U2 - 10.1016/S0008-6215(00)81073-3
DO - 10.1016/S0008-6215(00)81073-3
M3 - Article
AN - SCOPUS:0001226736
VL - 106
SP - 193
EP - 201
JO - Carbohydrate Research
JF - Carbohydrate Research
SN - 0008-6215
IS - 2
ER -