Unusual dimerization of N-protected bromomethylindoles/benzyl bromide with arylmetal halides: generation of indolylmethyl/benzyl radical

Neelamegam Ramesh, Chandran Prakash, Radhakrishnan Sureshbabu, Vasudevan Dhayalan, Arasambattu K. Mohanakrishnan

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

A detailed study on the interaction of N-protected bromomethylindoles with various types of aryl/alkyl Grignard is reported. Full experimental details on the mechanism of the unusual dimerization reaction are presented.

Original languageEnglish (US)
Pages (from-to)2071-2079
Number of pages9
JournalTetrahedron
Volume64
Issue number9
DOIs
StatePublished - Feb 25 2008

Keywords

  • Alkyl/aryl Grignard
  • Benzylbromide
  • Bromomethylindole
  • Indolylmethyl/benzyl radical

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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