Abstract
Over 140 rotational transitions have been assigned and measured for the ONO′ bending mode (ν7) of gaseous nitric acid. These observations, over a wide range of J and K values in the region 100-600 GHz, have been used as the basis for an analysis of the rotational structure of this vibrational state. The resulting rotation-distortion parameters make possible the calculation, with good accuracy, of all the transition frequencies arising from thermally populated levels of the ν7 vibrational state. Also, a novel spectrometer capable of broad spectral scans in the millimeter and submillimeter region is described.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 62-67 |
| Number of pages | 6 |
| Journal | Journal of Molecular Spectroscopy |
| Volume | 128 |
| Issue number | 1 |
| DOIs | |
| State | Published - Mar 1988 |
| Externally published | Yes |
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
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Cite this
Booker, R. A., Crownover, R. L., de Lucia, F. C., & Helminger, P. (1988). Millimeter- and submillimeter-wave spectra of the ONO′ bending mode (ν7) in nitric acid. Journal of Molecular Spectroscopy, 128(1), 62-67. https://doi.org/10.1016/0022-2852(88)90205-6