Conformational studies on aldonolactones by n.m.r. spectroscopy. Conformations of d-glucono-1,5-lactone and d-mannono-1,5-lactone in solution

Zbigniew Wałaszek, Derek Horton, Irena Ekiel

Research output: Contribution to journalArticlepeer-review

49 Scopus citations

Abstract

The conformations of d-glucono-1,5-lactone (1) and d-mannono-1,5-lactone (2) in solution were investigated by 1H- and 13C-n.m.r. spectroscopy. Conformational equilibria for 1 and 2 were found to lie strongly in favor of the 4H3(d),gg and B2,5(d),gg conformations, respectively.

Original languageEnglish (US)
Pages (from-to)193-201
Number of pages9
JournalCarbohydrate Research
Volume106
Issue number2
DOIs
StatePublished - Aug 16 1982
Externally publishedYes

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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