Analytical Characterization of Size-Dependent Properties of Larger Aqueous Gold Nanoclusters

Germán Plascencia-Villa, Borries Demeler, Robert L. Whetten, Wendell P. Griffith, Marcos Alvarez, David M. Black, Miguel José-Yacamán

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20 Scopus citations

Abstract

Gold nanoclusters (AuNCs) with well-defined structure and arrangement possess particular physical and functional properties. AuNCs that differ only by less than 1 nm in diameter corresponding to one atomic layer show different structural, optical, and physicochemical properties in a size-dependent mode, making their analytical characterization a challenge. Herein we describe an integrative approach to characterization of larger aqueous AuNC (Au102-pMBA44, Au144pMBA60 and higher) selected by gel electrophoresis (PAGE). We employ UV-vis, dynamic light scattering, and zeta-potential in combination with high-performance analytical techniques such as multiwavelength analytical ultracentrifugation and electrospray ionization mass spectrometry were used to separate aqueous AuNCs and to determine their specific hydrodynamic diameter, partial abundance, molecular weight, and mass/charge ratios when present in a complex mixture of AuNCs containing Au102 (1.6 nm), Au144 (2 nm), and Au288-328 (2.5 nm). Advanced analytical electron microscopy imaging (spherical aberration corrected BF/HAADF-STEM at low voltages dose) also revealed the structures of discrete arrangements of gold nanocluster populations.

Original languageEnglish (US)
Pages (from-to)8950-8958
Number of pages9
JournalJournal of Physical Chemistry C
Volume120
Issue number16
DOIs
StatePublished - Apr 28 2016

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Plascencia-Villa, G., Demeler, B., Whetten, R. L., Griffith, W. P., Alvarez, M., Black, D. M., & José-Yacamán, M. (2016). Analytical Characterization of Size-Dependent Properties of Larger Aqueous Gold Nanoclusters. Journal of Physical Chemistry C, 120(16), 8950-8958. https://doi.org/10.1021/acs.jpcc.6b00448